Publications
Inicio Publications
– L. Mallón, J. Navarro-Ruiz, C. Cerezo-Navarrete, N. Romero, I. del Rosal, J. García-Antón, R. Bofill, L. M. Martínez-Prieto*, K. Philippot,* R. Poteau* and X. Sala*, ACS Appl. Mat. Interf. 2025, 17, 6198. https://pubs.acs.org/doi/full/10.1021/acsami.4c15547
– Surface Functionalized Metal Catalysts. Ed: Luis M. Martínez Prieto. Topics in Organometallic Chemistry, 2024. https://doi.org/10.1007/978-3-031-73841-8
– Magnetic Nanoparticles and Radio Frequency Induction: From Specific Heating to Magnetically Induced Catalysis. J. Mazarío, S. Ghosh, V. Varela-Izquierdo, L. M. Martínez-Prieto* and B. Chaudret*, ChemCatChem. 2024, e202400683. https://doi.org/10.1002/cctc.202400683
– Structural transformation of carbon-encapsulated core-shell CoNi nanoparticles during magnetically induced CO2 reduction into CO. C. Cerezo-Navarrete, I. M. Marin, C. Marini, B. Chaudret*, L. M. Martínez-Prieto*, Appl. Catal. B: Environm. 2024, 347, 123780. https://doi.org/10.1016/j.apcatb.2024.123780
– A High Pressure Operando Spectroscopy Examination of Bimetal Interactions in ‘Metal Efficient’ Palladium/In2O3/Al2O3 Catalysts for CO2 Hydrogenation. M. E. Potter, S. Mediavilla Madrigal, E. Campbell, L. J. Allen, U. Vyas, S. Parry, A. García-Zaragoza, Luis M. Martínez-Prieto, P. Oña-Burgos, M. Lützen, C. D. Damsgaard, E. Rodríguez-Castellón, N. Schiaroli, G. Fornasari, P. Benito, A. M. Beale* Angew. Chem. Int. Ed. 2023, 62, e202312645. https://doi.org/10.1002/anie.202312645
– Boosting the catalytic performance of graphene-supported Pt nanoparticles via decorating with –SnBun: an efficient approach for aqueous hydrogenation of biomass-derived compounds. A. García-Zaragoza, C. Cerezo-Navarrete, P. Oña-Burgos, Luis M. Martínez-Prieto* Nanoscale. 2023, 15, 12319-12332. https://doi.org/10.1039/D3NR02083E
– Ruthenium nanoparticles canopied by heptagon-containing saddle-shaped nanographenes as efficient aromatic hydrogenation catalysts. C. Cerezo-Navarrete, A. David, A. García-Zaragoza, P. Oña-Burgos, I. del Rosal, R. Poteau, A. Campaña, Luis M. Martínez-Prieto* Chem. Sci. 2022, 13, 13046-13059. https://doi.org/10.1039/D2SC04228B
– Magnetically Induced Catalytic Reduction of Biomass-derived Oxygenated Compounds in Water. C. Cerezo-Navarrete, I. Mustieles, H. García Miquel, A. Corma, B. Chaudret, Luis M. Martínez-Prieto* ACS. Catal. 2022, 12, 8462. Front cover. https://doi.org/10.1021/acscatal.2c01696.
– Tailoring graphene-supported Ru nanoparticles by functionalization with pyrene-tagged N-heterocyclic carbenes. A. García-Zaragoza, C. Cerezo-Navarrete, A. Mollar-Cuni, P. Oña-Burgos, J. A. Mata, A. Corma, L. M. Martínez-Prieto* Catal Sci. Tech. 2022, 12, 1257-1270. Featured in Emerging Investigator Series 2022. https://doi.org/10.1039/D1CY02063C
– Ru nanoparticles supported on alginate-derived graphene for the hydrogen evolution reaction. L. Mallón, C. Cerezo-Navarrete, N. Romero, M. Puche, J. García-Antón, R. Bofill,* K. Philippot,* L. M. Martínez-Prieto,* X. Sala* New J. Chem. 2022, 46, 49. Front cover. Open Access. https://doi.org/10.1039/D1NJ05215B
– Metal Nanoparticle Catalysis. P.Lara,* L. M. Martínez-Prieto,* Catalysts 2021, 11, 1210. Editorial.
– Nucleophilic Nickel and Palladium pincer hydroxides: A study of their reactions with dimethyl carbonate and other non-alkylating organic electrophiles. L. M. Martínez-Prieto, D. del Rio, E. Álvarez, P. Palma, J. Cámpora* Eur. J. Inorg. Chem. 2021, 29, 2958. Open Access. https://doi.org/10.1002/ejic.20210
– A combined theoretical/experimental study highlighting the formation of carbides on Ru nanoparticles during CO hydrogenation. I.-T. Moraru,* L. M. Martínez-Prieto,* Y. Coppel, B. Chaudret, L. Cusinato, I. del Rosal, R. Poteau* Nanoscale. 2021, 13, 6902. https://doi.org/10.1039/D0NR08735A
– Heterolytic Cleavage of Dihydrogen (HCD) in Metal Nanoparticle Catalysis. I. Cano,* L. M. Martínez-Prieto,* P. W. N. M. van Leeuwen, Perspectives Catal Sci. Tech. 2021, 11, 1157. https://doi.org/10.1039/D0CY02399J
– Controlling the Selectivity of Bimetallic Platinum-Ruthenium Nanoparticles Supported on N-Doped Graphene by Adjusting their Metal Composition. C. Cerezo, Y. Mathieu, M. Puche, C. Morales, P. Concepción, L. M. Martínez-Prieto,* A. Corma, Catal Sci. Tech. 2021, 11, 494. Inside front cover. Open Access. https://doi.org/10.1039/D0CY02379E
– Organometallic Nanoparticles Ligated by NHCs: Synthesis, Surface Chemistry and Ligand Effects. C. Cerezo-Navarrete, P.Lara,* L. M. Martínez-Prieto,* Catalysts 2020, 10, 1144. https://doi.org/10.3390/catal10101144
– Ultrastable Magnetic Nanoparticles Encapsulated in Carbon for Magnetically Induced Catalysis. L. M. Martínez-Prieto, J. Marbaix, J. M. Asensio, C. Cerezo-Navarrete, P.-F. Fazzini, Katerina Soulantica, B. Chaudret,* A. Corma* ACS Appl. NanoMat. 2020, 3, 7076. https://doi.org/10.1021/acsanm.0c01392
– Nickel and Palladium Complexes with Reactive σ-Metal-Oxygen Covalent Bonds. L. M. Martínez-Prieto, J. Cámpora* Isr. J. Chem. 2020, 60, 373. https://doi.org/10.1002/ijch.202000001
– Novel Nickel Nanoparticles Stabilized by Imidazolium-Amidinate Ligands for Selective Hydrogenation of Alkynes. A. M. López-Vinasco, L. M. Martínez-Prieto,* J. M. Asensio, P. Lecante, B. Chaudret, J. Cámpora, P. W. N. M. van Leeuwen* Catal Sci. Tech. 2020, 10, 342-350. Featured as hot article (inside front cover). Open Access. https://doi.org/10.1039/C9CY02172H
– Tuning the Catalytic Activity and Selectivity of Water-Soluble Bimetallic RuPt Nanoparticles by Modifying their Surface Metal Distribution. D. Bouzouita, G. Lippens, E. A. Baquero, P. F. Fazzini, G. Pieters, Y. Coppel, P. Lecante, S. Tricard,* L. M. Martínez-Prieto,* B. Chaudret* Nanoscale. 2019, 11, 16544-16552. https://doi.org/10.1039/C9NR04149D
– Uniform Ru Nanoparticles on N-Doped Graphene for Selective Hydrogenation of Fatty Acids to Alcohols. L. M. Martínez-Prieto,* M. Puche, C. Cerezo-Navarrete, B. Chaudret, J. Catal. 2019, 377, 429. https://doi.org/10.1016/j.jcat.2019.07.040
– Reactions of D2 with 1,4-Bis(diphenylphosphino)butane stabilized Metal Nanoparticles – A combined gas-phase NMR, GC-MS and solid-state NMR Study. N. Rothermel, T. Röther, T. Ayvali, L.M. Martínez-Prieto, K. Philippot, H.-H. Limbach, B. Chaudret, T. Gutmann, G. Buntkowsky* ChemCatChem 2019, 11, 1465. https://doi.org/10.1002/cctc.201801981
– Monomeric Alkoxide and Alkylcarbonate Complexes of Nickel and Palladium Stabilized with the iPrPCP Pincer Ligand: A Model for the Catalytic Carboxylation of Alcohols to Alkyl Carbonates. L. M. Martínez-Prieto, P. Palma, J. Cámpora* Dalton Trans. 2019, 48, 1351. https://doi.org/10.1039/C8DT04919J
– Ruthenium nanoparticles ligated by cholesterol-derived NHCs and their application in the hydrogenation of arenes. L. M. Martínez-Prieto, L. Rakers, A. M. López-Vinasco, K. Philippot, P. W. N. M. van Leeuwen, B. Chaudret,* F. Glorius* Chem. Commun. 2018, 54, 7070. Highlighted in ChemistryViews. https://doi.org/10.1039/C8CC02833H
– Ruthenium-Catalyzed Hydrogen Isotope Exchange of C(sp3)-H Bonds Directed by a Sulfur Atom. L. Gao, S. Perato, S. Garcia-Argote, C. Taglang, L. M. Martínez-Prieto , C. Chollet, D.-A. Buisson, V. Dauvois, P. Lesot, B. Chaudret, B. Rousseau, S. Feuillastre, G. Pieters* Chem. Commun. 2018, 54, 2986. https://doi.org/10.1039/C8CC00653A
– Organometallic Ru Nanoparticles: Synthesis, Surface Chemistry and Insights into Ligand Coordination. L. M. Martínez-Prieto, B. Chaudret* Acc. Chem. Res. 2018, 51, 376-384. https://doi.org/10.1021/acs.accounts.7b00378
– An Iridium–SPO Complex as Bifunctional Catalyst for the Highly Selective Hydrogenation of Aldehydes. I. Cano,* L. M. Martínez-Prieto, L. Vendier, P. W. N. M. van Leeuwen* Catal. Sci. & Tech. 2018, 8, 221. https://doi.org/10.1039/C7CY01953J
– Nickel Pincer Complexes with Frequent Aliphatic Alkoxo Ligands [(iPrPCP)Ni-OR] (R = Et, n-Bu, i-Pr, 2-hydroxyethyl). An Assessment of the Hydrolytic Stability of Nickel and Palladium Alkoxides. L. M. Martínez-Prieto, P. Palma, E. Alvarez, J. Cámpora* Inor. Chem. 2017, 56, 13086. https://doi.org/10.1021/acs.inorgchem.7b01868
– Characterization of Secondary Phosphine Oxide Ligands on the Surface of Iridium Nanoparticles. I. Cano,* L. M. Martínez-Prieto, P. F. Fazzini, Y. Coppel, B. Chaudret, P. W. N. M. van Leeuwen*, PCCP 2017, 19, 21655. https://doi.org/10.1039/C7CP03439C
– Soluble Platinum Nanoparticles ligated by Long-Chain N-Heterocyclic Carbenes as Catalysts. L. M. Martínez-Prieto, L. Rakers, A. M. López-Vinasco, I. Cano, Y. Coppel, K. Philippot, F. Glorius,* B. Chaudret,* P. W. N. M. van Leeuwen, Chem. -A Eur. J. 2017, 23, 12779. Accepted as hot paper (front cover picture). https://doi.org/10.1002/chem.201702288
– Monitoring Nanoparticle Reactivity in Solution: Interaction of L-lysine and Ru Nanoparticles Probed by Chemical Shift Perturbation parallels regioselective H/D exchange. L. M. Martínez-Prieto,* E. A. Baquero, G. Pieters, J. C. Flores, E. de Jesús, C. Nayral, F. Delpech, P. W. N. M. van Leeuwen, G. Lippens,* B. Chaudret*, Chem. Commun. 2017, 53, 5850. https://doi.org/10.1039/C7CC02445B
– Zwitterionic amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts. L. M. Martínez-Prieto,* I. Cano, A. Márquez, E. A. Baquero, S. Tricard, L. Cusinato, I. del Rosal, R. Poteau, Y. Coppel, K. Philippot, B. Chaudret, J. Cámpora, P. W. N. M van Leeuwen*, Chem. Sci. 2017, 8, 2931. Open Access. Highlighted in Synfacts as “synfact of the month”; 2017, 13(07): 0765. Highlighted as Supporting citation in Scite. https://doi.org/10.1039/C6SC05551F
– Iridium vs. Iridium: Nanocluster and Monometallic Catalysts Carrying the Same Ligand Behave Differently. I. Cano, L. M. Martínez-Prieto, B. Chaudret, P. W. N. M van Leeuwen* Chem. -A Eur. J. 2017, 23, 1. https://doi.org/10.1002/chem.201605352
– Theoretical Characterization of the Surface Composition of Ruthenium Nanoparticles in Equilibrium with Syngas. L. Cusinato, L. M. Martínez-Prieto, B. Chaudret, I. del Rosal, R. Poteau* Nanoscale 2016, 8, 10974. https://doi.org/10.1039/C6NR01191H
– NHCs-stabilized Ru nanoparticles: synthesis and surface studies. P. Lara,* L. M. Martínez-Prieto*, M. Roselló-Merino, C. Richter, F. Glorius, S. Conejero, K. Philippot, B. Chaudret, NanoSO 2016, 6, 39. https://doi.org/10.1016/j.nanoso.2016.03.003
– Long-chain NHC-stabilized RuNPs as versatile catalysts for one-pot oxidation/hydrogenation reactions. L. M. Martínez-Prieto, A. Ferry, C. Richter, K. Philippot* B. Chaudret,* F. Glorius,* Chem. Commun. 2016, 52, 4768. Open Access. Highlighted in Synfacts; 2016, 12(06):0651. https://doi.org/10.1039/C6CC01130F
– Enantioselective hydrogenation of ketones by iridium nanoparticles ligated with chiral secondary phosphine oxides. I. Cano, M. J.-L. Tschan, L. M. Martínez-Prieto, K. Philippot, B. Chaudret, P. W. N. M. van Leeuwen* Catal. Sci. & Tech. 2016, 6, 3758. https://doi.org/10.1039/C5CY02206A
– Enantiospecific C‒H activation using ruthenium nanocatalysts. C. Taglang, L. M. Martínez-Prieto, I. del Rosal, L. Maron, R. Poteau, K. Philippot, B. Chaudret, S. Perato, C. Puente, C. Duga, B. Rousseau, G. Pieters* Angew. Chem. Int. Ed. 2015, 54, 10474. Published as VIP (front cover picture). Highlighted in Synfacts 2015, 11(12): 1329. https://doi.org/10.1002/anie.201504554
– New route to stabilize ruthenium nanoparticles with non-isolable chiral N-heterocyclic carbenes. L. M. Martínez-Prieto, A. Ferry, P. Lara, C. Richter, K. Philippot,* F. Glorius,* B. Chaudret* Chem. -A Eur. J. 2015, 21, 17495. https://doi.org/10.1002/chem.201502601
– β-Hydrogen elimination reactions of nickel and palladium methoxides stabilised by PCP pincer ligands. L. M. Martínez-Prieto, E. Ávila, P. Palma, E. Alvarez, J. Cámpora* Chem. -A Eur. J. 2015, 21, 9833. https://doi.org/10.1002/chem.201500652
– A Betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce ultra-small ruthenium nanoparticles. L. M. Martínez-Prieto, C. Urbaneja, P. Palma, J. Cámpora,* K. Philippot,* B. Chaudret* Chem. Commun. 2015, 51, 464. https://doi.org/10.1039/C5CC00211G
– Organometallic Ruthenium Nanoparticles as Model Catalysts for CO Hydrogenation: A Nuclear Magnetic Resonance and Ambient-Pressure X-ray Photoelectron Spectroscopy Study. L. M. Martínez-Prieto, S. Carenco, C. H. Wu, E. Bonnefille, S. Axnan-da, Z. Liu, P. F. Fazzini, K. Philippot, M. Salmeron,* B. Chaudret* ACS Catalysis 2014, 4, 3016. https://doi.org/10.1021/cs5010536
– Reversible reactions of Ni and Pd hydroxo pincer complexes [(iPrPCP)M-OH] with CO2: solid-state study of the decarboxylation of the monomeric bicarbonate complexes [(iPrPCP)M-OCOOH] (M = Ni, Pd.). L. M. Martínez-Prieto, C. Real, E. Ávila, P. Palma, J. Cámpora,* E. Alvarez Eur. J. Inorg. Chem. 2013, 32, 5555. https://doi.org/10.1002/ejic.201300995
– Synthesis and reactivity of nickel and palladium fluoride complexes with PCP pincer ligands. NMR-based assessment of electron-donating properties of fluoride and other monoanionic ligands. L. M. Martínez-Prieto, C. Melero, D. del Rio, P. Palma, J. Cámpora,* E. Alvarez Organometallics 2012, 31, 1425. https://doi.org/10.1021/om2009793
– Selective reduction of a Pd pincer PCP complex to well-defined Pd(0) Species. C. Melero, L. M. Martínez-Prieto, P. Palma, D. del Rio, E. Alvarez, J. Cámpora* Chem. Commun. 2010, 46, 8851. https://doi.org/10.1039/C0CC02972F
– Palladium(II) carboxylates and palladium(I) carbonyl carboxylate complexes as catalysts for olefin cyclopropanation with ethyl diazoacetate. O. Shishilov, T. A. Stromnova, J. Cámpora,* P. Palma, M. A. Cartes, L. M. Martínez-Prieto Dalton Trans. 2009, 6626. https://doi.org/10.1039/B904891J
– A study of the non-electrostatic interaction micelle/charged ligand: a comparison of the results obtained by two different methods. R. Jiménez,* D. Villegas, L. M. Martínez-Prieto, H. K. Stürckow, F. Lería, J. Morales, Chem. Phys. Lett. 2006, 417, 509. https://doi.org/10.1016/j.cplett.2005.10.074